Who do you want to notify?
But, yes, as kenlars said, it is not something the IVE can do; you would need to configure a 3rd-party system to perform that action.
Not from the SA.
You could use something which postprocesses syslog and have it send an email upon receiving the syslog message which is generated upon logon. I'm pretty sure the Kiwi syslog tool can do that, and probably so can others.